
Fluorine
Element | Fluorine |
Symbol | F |
Atomic Number | 9 |
Molar Mass | 19 gmol-1 |
Electron Configuration | [He]2s22p5 |
Normal State | gas nonmetal |
Density @STP | 1.7x10-3 g cm-3 |
Melting Point | -220oC |
Boiling Point | -188oC |
Stable Isotopes | 19F |
Atomic Radius | 64 pm |
Ionic Radius | 133 (1-) pm |
Electronegativity (Pauling) | 4 |
Ionization Energy (1st) | 1681 kJ mol-1 |
Ionization Energy (2nd) | 3374 kJ mol-1 |
Ionization Energy (3rd) | 6050 kJ mol-1 |
Molar Heat Capacity | 22.7 J K-1mol-1 |
Standard Molar Entropy | 158.8 J K-1mol-1 |
Enthalpy of Fusion | 5.1 kJ mol-1 |
Enthalpy of Vapourization | 6.548 kJ mol-1 |
[Back to Periodic table]
- Fluorine is a highly toxic pale yellow diatomic halogen gas
- Fluorine discovery by André-Marie Ampère (1810)
- Fluorine first isolated by Henri Moissan (1886)
- Fluorine named by Humphry Davy after the mineral fluorite, itself named after Latin fluo (to flow, in smelting)
- Fluorine is the most electronegative element, extremely reactive with almost all other elements, including some noble gases
- Fluorine ranks 24th in universal abundance and 13th in terrestrial abundance
- Fluorite, the primary mineral source of fluorine which gave the element its name as it was added to metal ores to lower their melting points for smelting
- Most commercial applications use fluorine compounds, with about half of mined fluorite used in steelmaking
- Fluorine combines with metals, nonmetals, metalloids, some noble gases and usually assumes an oxidation state of -1
- Fluorine's high electron affinity results in a preference for ionic bonding and when it forms covalent bonds, these are polar, and almost always single
- Carbon–fluorine forms organic chemistry's strongest bond and gives high stability to organofluorines
- Organofluorines are almost non-existent in nature, but are used in artificial compounds with many commercial applications
- Fluorocarbons (perfluorocarbons, PFCs) contain only carbon and fluorine (replacing hydrogen in hydrocarbons)
- Fluorocarbons and their derivatives are used as fluoropolymers, refrigerants, solvents, and anesthetics
- Polytetrafluoroethylene (PTFE), sometimes called by its DuPont name Teflon represents 60–80% by mass of the world's fluoropolymer production
- Hydrogen and fluorine combine to yield hydrogen fluoride which readily hydrates on contact with water to form highly corrosive hydrofluoric acid
- Fluorocarbon gases are generally greenhouse gases with global-warming potentials
- Fluorine is used in agrichemicals most of them herbicides and fungicides with a few crop regulators
- Fluorine is used in fluorosurfactants used for repelling water and stains
- Fluorides are used dental care, water fluoridation, toothpastes
- Fluorine is not essential for humans or other mammals, tiny amounts may be beneficial for teeth and bones
- Elemental fluorine and hydrofluoric acid is highly toxic and corrosive to living organisms


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